Docket #: S24-356
Production of Carbon Material from Low Concentration CO2 via Microbial CO2 Reduction and Pyrolysis
Stanford researchers have developed a novel pathway to upcycle waste CO2 into graphitic carbon nanomaterials. Addressing the urgent challenge of rising atmospheric CO2 levels, this process transforms dilute CO2 streams, such as air or flue gases, into an industrially valuable product. Carbon nanomaterials do not readily decompose and can therefore act as semi-permanent carbon storage depending on end-use.
The pathway uniquely integrates biological and thermochemical transformations. It pioneers the use of microbes for CO2 conversion directly from CO2 captured in alkaline solution. Powered by H2, biotrickling filters with alkaliphilic hydrogenotrophic methanogenic archaea and hydrogen-oxidizing bacteria convert CO2 to methane. The produced methane is then pyrolyzed to form carbon. Compared to alternative CO2 capture and use pathways, this pathway avoids intermediate product separations and produces high quality carbon from dilute CO2 feedstocks.
This technology is an appealing solution to convert and store waste CO2 as valuable carbon nanomaterials, a material in high demand for use in electronics, batteries, and building materials.
See Related Technologies:
A semi-continuous process for co-production of CO2-free hydrogen and carbon nanotubes via methane pyrolysis
Microbial-driven atmospheric CO2 conversion for large-scale carbon sequestration
Stage of Development: Proof of concept
Applications
- Upcycling waste CO2
- Sustainability and environmental goals
- Fossil-free, independent carbon material sourcing
Advantages
- Works with a supply of low concentration CO2
- Produces high-value carbon, such as multiwalled carbon nanotubes (MWCNTs)
Publications
- Grace Callander, Jörg S. Deutzmann, Alfred M. Spormann (2024), Alkaline hydrogenotrophic Methanogenesis in Methanococcus vannielii at low carbon dioxide concentrations, Journal of CO2 Utilization 83, 102788
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