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Docket #: S20-002

Ultratrace and Multiplex Visual/Smartphone Detection of Heavy Metal Ions by their Sulfidation on a Superhydrophobic Concentrator

Stanford researchers have developed a portable sensor device for rapid detection of heavy metal ions using a sulfidation process and concentrator for increased visual detection. The device achieves ultratrace and multiplex quantification of Pb2+, Ni2+, Cr3+, Cu2+ and Co2+ in 8 minutes with 90% accuracy and only requires 5 microliters of sample. The device contains four components: 1) a superhydrophobic concentrator (SPOT) sensor, 2) a miniature droplet heater, 2) a portable microscope, and 4) a smartphone image analyzer. In contrast to conventional optical sensors, this device's mobility allows for on-site testing of wastewater, groundwater, and soil etc. The unique SPOT concentrator continuously accumulates the heavy metal sulfides making visual detection easy down to a lower detection limit of 0.1 nanomolar, 3-6 orders of magnitude higher than WHO and EPA permissible levels. This device is applicable for field testing and other environmental monitoring purposes.

Stage of Research

  • Prototype
  • Applications

    • On-site detection of heavy metal ions in water or soil
    • Concurrent quantification of multiple heavy metal ion species
    • Quick comprehensive analysis: 8 minutes and 90% accuracy

    Advantages

    • Quantifies concentrations from 0.1 nanomolar to 1 millimolar for Pb2+, Ni2+, Cr3+, Cu2+ and Co2+
    • Concentrates analytes to improve visual detection sensitivity
    • Only requires 5 microliter samples
    • Low cost sulfidation reagent reduces overall cost vs conventional optical sensors
    • Reusable: concentrator only requires acidic wash to clean

    Publications

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